This review study considers the classification of data on synthesis methods and practically valuable features of
glycoluril-based macrocyclic nitrogen-containing compounds as precursors for polymeric compounds. General
data about glycoluril and tetra-N-hydroxymethylglycoluril as parental bases for various macrocyclic compounds
were considered. Generalized experimental facts about methods for glycoluril direct N-functionalization and its
N-hydroxymethyl derivative reactions in macrocycles and polymeric compound synthesis are given