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Browsing НИИ прикладной химии by Author "Adekenov, S. M."

Browsing НИИ прикладной химии by Author "Adekenov, S. M."

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  • Suleimenov, E. M.; Raldugin, V. A.; Shakirov, M. M.; Bagryanskaya, I. Yu.; Gatilov, Yu. V.; Kulyjiasov, A. T.; Adekenov, S. M. (2014-06-30)
    Oxidation of (+) sabinol, (1S,3R,5S)-1-isopropyl-4-methylidenebicyclo[3.1.0]hexan-3-ol, by active MnO2 afforded not the expected sabinone but only its [4+2]-cyclodimer. The molecular structure of the latter was established ...
  • Suleimenov, E. M.; Smagulova, F. M.; Seidakhmetova, R. B.; Aksartov, R. M.; Raldugin, V. A.; Adekenov, S. M. (2014-07-02)
    Artemisia sieversianaWilld (Sievers wormwood) is a large weed that inhabits almost all of Kazakhstan. Guaianolides, the lignans sieversol and 5-methoxysesamin, coumarins, and the essential oil, for which the component ...
  • Suleimenov, E. M.; Raldugin, V. A.; Gatilov, Yu. V.; Bagryanskaya, I. Yu.; Seidakhmetova, R.; Aksartov, R. M.; Adekenov, S. M. (2014-07-02)
    Reaction of the germacranolide stizolicin with secondary amines formed normal products of a Michael reaction at the exomethylene group and simultaneously led to solvolysis with cleavage of the acyl group. The structures ...
  • Suleimenov, E. M.; Raldugin, V. A.; Adekenov, S. M. (2014-07-02)
    We isolated previously from Artemisia albidaWilld. the sesquiterpene lactones austricin, matricarin, canin, and argolide in addition to the flavonoids eupatilin and its 5′-methyl ester.
  • Asanova, Zh. K.; Suleimenov, E. M.; Atazhanova, G. A.; Dembitskii, A. D.; Pak, R. N.; Dar, A.; Adekenov, S. M. (2014-07-02)
    Levant (santonica) wormwood (Artemisia cina Berg.) is known as the source of an antihelminthic agent. Wild-growing plants are now encountered only in South Kazakhstan and in the Zhambyl Regions of Kazakhstan. The above-ground ...
  • Seidakhmetova, R. B.; Beisenbaeva, A. A.; Atazhanova, G. A.; Suleimenov, E. M.; Pak, R. N.; Kulyyasov, A. T.; Adekenov, S. M. (2014-06-30)
    Essential oils are complex mixtures of various organic compounds, most of which possess an isoprenoid structure. Data in the literature are indicative of the high biological activity of essential oils, which makes possible ...
  • Suleimenov, E. M.; Raldugin, V. A.; Adekenov, S. M. (2014-07-03)
    The sesquiterpene lactones stizolicin, stizolin, and balsamin were isolated previously by Rybalko from Stizolophus balsamita (Lam.) Cass. ex. Takht.
  • Suleimenov, E. M.; Ozek, T.; Demirci, F.; Demirci, B.; Baser, K. H. C.; Adekenov, S. M. (2014-07-03)
    Artemisia kasakorum (Krasch.) Pavlov is a rhizomous grayish-green perennial of up to 80 cm height with a few thick and strong generative runners. The endemic Turanian species is ecologically confined to strongly saline ...
  • Sadyrbekov, D. T.; Suleimenov, E. M.; Tikhonova, E. V.; Atazhanova, G. A.; Tkachev, A. V.; Adekenov, S. M. (2014-07-02)
    The component composition of the four speciesAchillea filipendulina, A. sudetica, A. ledebourii, and A. cartilaginea was studied by GC-MS. It was found that the principal components of the essential oil (%) were santolina ...
  • Suleimenov, E. M.; Ozek, T.; Demirci, F.; Demirci, B.; Baser, K. H. C.; Adekenov, S. M. (2014-07-03)
    In continuation of the study of the composition of essential oils from plants of the Kazakhstan flora, the component compositions of two types of sage, A. lercheanaKar. et Kir. and A. sieversianaWilld., were investigated by GC—MS.
  • Suleimenov, E. M.; Raldugin, V. A.; Shakirov, M. M.; Adekenov, S. M. (2014-07-03)
    The sidechain of the germacranolide stizolicin was oxidized by CrO3 in Py to form a lactone. The structure of the product was established as 4,5α-epoxy-7α,5,6,8β(H)-germacr-1(10),11(13)-dien-8α(3′-oxo-2′,5′-dihydrofuran- ...
  • Suleimenov, Ye. M.; Atazhanova, G.A.; Ozek, T.; Demirci, B.; Kulyyasov, A.T.; Adekenov, S. M.; Baser, K.H.C. (2014-06-30)
    The chemical composition of essential oils of Achillea millefolium L., A. nobilis L. from Kazakhstan flora and A. grandiflora Bieb introduced in culture at the Karaganda Botanic garden were determined by GC/MS. The main ...
  • Suleimenov, E. M.; Tkachev, A. V.; Adekenov, S. M. (2014-07-03)
    Essential oil from the aerial part of Siberian wild and cultivated Artemisia dracunculus L. (AD, tarragon) was studied previously by GC–MS.
  • Suleimenov, E. M.; Atazhanova, G. A.; Kulyyasov, A. T.; Raldugin, V. A.; Bagryanskaya, I. Yu.; Gatilov, Yu. V.; Shakirov, M. M.; Adekenov, S. M. (2014-07-02)
    (3aR*,6aR*)-3,3,5,5-Tetramethyl-3a,6a-dinitro-3a,6a-dihydro-3H-cyclopentano[c]pyrazol-2-oxide was formed by reaction of cycloartemisiaketone oxime [4,4-dimethyl-2-(1-methylethylidene)cyclopentanone oxime] with AcOH and ...
  • Dzhalmakhanbetova, R. I.; Suleimenov, E. M.; Rakhimova, B. B.; Talzhanov, N. A.; Kulyyasov, A. T.; Adekenov, S. M. (2014-06-30)
    Novel dialkylphosphonates of arteannuin B were synthesized in 45-47% yields by reaction of thiscadinanolide with dialkylphosphites. Their structures were established using IR, PMR, C and P NMR spectroscopy, and two-dimensional ...
  • Luzina, O. A.; Adekenov, S. M.; Suleimenov, E. M.; Atazhanova, G. A.; Salakhutdinov, N. F.; Barkhash, V. A. (2014-06-30)
    We previously examined photochemical reactions of some naturally occurring di- and trienones and their analogs, as well as the effect of complex formation with cyclodextrins on this process. All these ketones had a common ...
  • Suleimenov, E. M.; Smagulova, F. M.; Morozova, O. V.; Raldugin, V. A.; Bagryanskaya, I. Yu.; Gatilov, Yu. V.; Yamovoi, V. I.; Adekenov, S. M. (2014-07-02)
    The five known lactones matricarin, austricin, canin, and achillin guaianolides and argolide germacranolide and the two flavonoids eupatilin and its 7-O-methyl ester were isolated for the first time from the aerial part ...
  • Suleimenov, E. M.; Smagulova, F. M.; Morozova, O. V.; Raldugin, V. A.; Bagryanskaya, I. Yu.; Gatilov, Yu. V.; Yamovoi, V. I.; Adekenov, S. M. (2014-06-30)
    The five known lactones matricarin, austricin, canin, and achillin guaianolides and argolide germacranolide and the two flavonoids eupatilin and its 7-O-methyl ester were isolated for the first time from the aerial part ...
  • Suleimenov, E. M.; Morozova, O. V.; Raldugin, V. A.; Gatilov, Yu. V.; Rybalova, T. V.; Shakirov, M. M.; Seidakhmetov, R.; Aksartov, R. M.; Adekenov, S. M. (2014-06-30)
    Four sesquiterpene lactones with the germacrane structure were isolated from the aerial part ofStizolophus balsamita. X-ray structure analyses showed that two of them were previously known balsamin derivatives. A third was ...

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